三维DIC在GFRP锚杆拉伸力学性能测试中的应用

随着玻璃纤维增强塑料(GFRP)广泛运用于轨道交通及边坡加固中,其力学性能的测试显得尤为重要。基于三维数字图像相关(DIC)方法,研究了三种不同加载速率下GFRP锚杆的拉伸力学性能,分别得到了应力-应变曲线及弹性模量、抗拉强度、最大力总延伸率等参数。实验结果表明,螺旋状变截面锚杆的轴向应变呈非均匀分布,由三维DIC得到的锚杆弹性模量结果一致性优于传统的接触式引伸计方法,GFRP锚杆几乎呈线性分布的应力-应变曲线表明该材料为典型的脆性材料。     

Radical grafting from carbon fiber surface: graft polymerization of vinyl monomers initiated by azo groups introduced onto the surface

This paper describes the radical graft polymerizations of vinyl monomers from carbon fiber surface initiated by azo groups introduced onto the fiber surface. The carbon fiber used in this experiment was the polyacrylonitrile type. The introduction of azo groups onto the carbon fiber surface was achieved by the reaction of 4,4'-azobis (4-cyanopentanoic acid) with isocyanate groups which were previously attached onto the surface by the treatment of the fiber with tolylene 2,4-diisocyanate. The amount of surface azo groups introduced onto nitric acid-treated carbon fiber was determined to be 0.60 x 10^-5 mol 9^-1 by nitrogen analysis. The radical graft polymerization of methyl methacrylate (MMA) was tried. Though the thermal polymerization of MMA proceeded slightly in the absence or in the presence of untreated carbon fiber, the rate of the polymerization was considerably low. In contrast, the graft polymerization of MMA was initiated in the presence of the carbon fiber having surface azo groups, and part of resultant poly(MMA) grafted onto the surface. The percentage of grafting increased with an increase in polymerization time and reached 42.8% after 24 h. The graft polymerizations of other monomers, such as styrene, vinyl acetate, and acrylic acid, were also initiated by the surface azo groups attached onto the carbon fiber, and the corresponding polymer effectively grafted onto the surface.     

Geometric Generalization of the Exponential Law

For the multivariate ℓ₁-norm symmetric distributions, which are generalizations of the n-dimensional exponential distribution with independent marginals, a geometric representation formula is given, together with some of its basic properties. This formula can especially be applied to a new developed and statistically well motivated system of sets. From that the distribution of a t-statistic adapted for the two-parameter exponential distribution and its generalizations is determined. Asymptotic normality of this adapted t-statistic is shown under certain conditions.     

铁改性的Mo/ZSM-5催化剂上NO的选择性催化还原反应

采用浸渍法制备了Mo/ZSM-5, Fe/ZSM-5和不同Fe和Mo摩尔比的Fe-Mo/ZSM-5样品, 并以氨为还原剂对其NO选择性催化还原活性以及反应条件对催化性能的影响进行了研究. 结果表明, Fe-Mo/ZSM-5样品的NOx转化率明显比单独的Mo/ZSM-5和Fe/ZSM-5的高. 当n(Fe):n(Mo)为1.5时, Fe-Mo/ZSM-5样品具有最佳催化性能, 其NOx转化率在430 ℃时达到了96%, 并且能在高空速和不同O2气浓度的条件下保持高的催化活性. 同时采用XRD和XPS技术分别对催化剂的体相结构和表面性质进行了研究, 结果表明, 当n(Fe):n(Mo)=1.5时, Fe和Mo元素之间以及与载体HZSM-5之间存在较强的相互作用, 并且其表面的Mo3d的含量最高. 这可能与其高的催化活性有关. 另外还发现, 在反应过程中Fe-Mo/ZSM-5催化剂表面的氮氧物种主要是吸附态NO, 因此可以推测NO的催化还原反应机理是, 在催化剂表面上, 吸附态NO与吸附NH3物种直接反应生成氮气, 而非经过氧化为NO2的途径.     

注水油田年综合含水率预测的数学模型

本文将改进的灰色GM（1，1）模型用于某油田年综合含水率的近期发展趋势研究。在平均相对误差达到最小准则下，研究了模型中的背景值参数A和边值修正项￡对模型预测精度的影响。在此基础上，采用线性规划方法估计模型中的参数，基于遗传算法求解最佳背景值参数A和最佳边值修正项ε，以确保在相应的模型检验准则下预测的误差达到最小。结果表明，用改进的灰色GM（1，1）模型预测近期注水油田的综合含水率，预测值与实际值相对误差很小，预测精度很高，可以得到非常满意的结果。进一步的研究发现，改进的灰色GM（1，1）模型虽然近期预测精度很高，但研究长期的发展趋势是行不通的，为此又研究探讨了长期发展趋势模型。     

桑蚕种样本良卵数偏差控制方法研究

桑蚕种良卵率是蚕种质量检验的重要指标,控制样本间良卵数偏差是保证良卵率准确性的关键.运用概率理论,针对目前生产上绝大多数批次的良卵率p 99%情况,在置信概率为95%下,样本卵粒数在1601~1700、1701~1800、1801~1900、1901~2000区间内时,给出了样本良卵数的容许偏差分别为16、17、17、18粒;当良卵率p在99%~90%其他区间时,也分别给出了不同克卵粒数情况下样本良卵数的容许偏差.同时在置信概率为90%下,给出了不同克卵粒数情况下样本良卵数的容许偏差.结合实际调查结果,对理论方法进行了比较,确认了理论方法的准确性,为蚕业生产提供了一套控制良卵数偏差的可行性方案.     

Chemical composition and antioxidant activity of Borago officinalis L. leaf extract growing in Algeria

The aqueous and hydroalcoholic extracts of borage (Borago officinalis) leaves from Annaba region (Algeria) were preliminary analyzed for their phenolic profile (total phenolics, total flavonoids, total flavonols, total tannins and total anthocyanins). These extracts were evaluated for their antioxidant properties by different methods such as DPPH radical scavenging, test NBT and total antioxidant activity. The two extracts have exhibited a high antiradical capacity. Indeed, the ethanolic extract showed the lower IC50 values and the highest amount of phenolics (94.09 ± 1.72 mg gallic acid/g dry extract). Using LC-MS/MS analysis, it was possible to identify phenolic acids, flavonoids, sterol and for the first time oleuropein was identified in the aqueous extract of the plant. The obtained results have demonstrated that phenolic compounds are the major contributor to the antioxidant activity of plants.     

Comparing confidence limits for short-run process incapability index Cpp

Process incapability index C_pp has been proposed in the manufacturing industry to assess process incapability. In industries it is sometimes unable to get large samples, and, hence, the CAN (consistent and asymptotically normal) property of the unbiased estimator for C_pp is missing. In this paper, six bootstrap methods are applied to construct upper confidence bounds (UCBs) of C_pp for short-urn production processes where sample size is small; standard bootstrap (SB), Bayesian bootstrap (BB), bootstrap pivotal (BP), percentile bootstrap (PB), bias-corrected percentile bootstrap (BCPB), and bias-corrected and accelerated bootstrap (BCa). A numerical simulation study is conducted in order to demonstrate the performance of the six various estimation methods. We further investigate the accuracy of the six methods by calculating the relative coverage (defined as the ratio of coverage percentage to average length of UCB). Detailed discussions of simulation results for seven short-run processes are presented. Finally, one real example from Ford Company’s Windsor Casting Plant is used to illustrate the six interval estimation methods.     

Densities and isothermal compressibilities of ionic liquids—Modeling and application

Two corresponding-states forms have been developed for direct correlation function integrals in liquids to represent pressure effects on the volume of ionic liquids over wide ranges of temperature and pressure. The correlations can be analytically integrated from a chosen reference density to provide a full equation of state for ionic liquids over reduced densities from 1.5 to more than 3.6. One approach is empirical with 3 parameters, the other is a 2-parameter theoretical form which is directly connected to a method for predicting gas solubilities in ionic liquids. Parameters for both methods have been obtained for 28 different ionic liquid systems by reduction of carefully validated PρT data. The results show excellent agreement with the experimental data for nearly all substances over all ranges of conditions. Group contributions to parameters are also explored, leading to an entirely predictive method for ambient pressure densities and densities of compressed ionic liquids. Extensive comparisons are made with other techniques.     

偶氮型光致变色液晶树状大分子的量子产率、异构转化率和活化能研究

研究了化合物端基含36个己氧基偶氮苯介晶基元的二代(G2)光致变色液晶树状大分子在氯仿及四氢呋喃溶液中的量子产率、吸收光强Ia、活化能E、异构转化率A/A0、热回复异构化速率常数kH及其反/顺异构体组分比A′/A′0,并与一代光致变色液晶碳硅烷树状大分子(G1)及介晶基元化合物(M3)的光化学行为进行了比较.在氯仿及四氢呋喃溶液中的量子产率的顺序均为M3>G1>G2,吸收光强Ia在氯仿及四氢呋喃溶液中的顺序分别为G2>G1>M3(氯仿)和M3>G1>G2(四氢呋喃),在氯仿及四氢呋喃溶液中活化能的顺序均为M3>G2>G1,在氯仿及四氢呋喃溶液中热回复异构化速率常数kH的顺序均为G1>G2>M3,在热回复异构化反应中的反/顺异构体组分比A′/A0′在氯仿及四氢呋喃溶液中的顺序均为G2>G1>M3.